Lubrication solutions for threaded connections

DuPont Molykote® Lubricants

 

For over fifty years, OEM designers, maintenance engineers and materials engineers around the world have relied on the Molykote® brand for performance and lubrication expertise. Molykote lubricants, formulated for extreme loads and environments, are also ideal for standard lubrication. They offer additional benefits over conventional lubricants, including:

 

  • Longer component life
  • Longer lubricant life
  • Extended maintenance intervals
  • Reduced maintenance time and costs

 

With technical centres worldwide, our products can reach you wherever you are to provide Smart Lubrication™.

Improving the performance of threaded connections

 

Threaded connections offer benefits such as convenient disassembly, reuse and accurate reassembly. However, without proper lubrication, these benefits can be compromised, leading to equipment challenges and reliability issues.

Lubrication prevents problems such as:

 

  • Inconsistent friction coefficients, leading to uneven bolt tensioning
  • Stick-slip
  • Stress corrosion cracking
  • Fretting
  • Galling
  • Seizing

 

Molykote® lubricants help your threaded connections perform well, from initial assembly to repeated disassembly. They are designed to withstand harsh conditions, a wide range of temperatures and the effects of heavy loads and contaminants.

 

The benefits of effective lubrication

 

Lubricants reduce friction and wear, protect against corrosion and dissipate heat. The use of carefully selected lubricants helps prevent common failure mechanisms associated with threaded connections. The key functions of good lubrication are :

  • Provide a constant coefficient of friction (µ)
    • Minimise the complexity of achieving appropriate preload forces and torque specifications
    • Reduce fatigue failure rates through stability to temperature and load variations
  • Form protective barriers
    • Prevent scaling of threaded surfaces
  • Provide protective coatings on mating surfaces
    • Reduce fretting, corrosion, galling and shearing
    • Reduce exposure to corrosive environments

 

MOLYKOTE® ANTI-SEIZE PASTES PROVIDE A CONSTANT COEFFICIENT OF FRICTION

PRODUCT NAME µt µc K*
MOLYKOTE® G-n METAL ASSEMBLY PASTE/SPRAY 0.078 0.085 0.15
MOLYKOTE® G-n PLUS PASTE 0.12 0.06 0.14
MOLYKOTE® G-RAPID PLUS PASTE/SPRAY 0.10 0.06 0.13
MOLYKOTE® 1000 PASTE/SPRAY 0.13 0.08 0.17
MOLYKOTE® M-77 PASTE 0.12 0.12 0.20
MOLYKOTE® P-37 PASTE 0.142 0.091 0.18
MOLYKOTE® P-40 PASTE 0.16 0.08 0.18
MOLYKOTE® P-74 PASTE 0.117 0.078 0.16
MOLYKOTE® P-1900 PASTE / SPRAY 0.10 0.10 0.17
MOLYKOTE® U-n PASTE 0.11 0.11 0.18

 

Tightening torque

 

Adequate torque is required to achieve proper bolt tension and elongation. The torque must overcome all sources of friction before elongation can occur. Thread and bolt head friction can be reduced and held constant by the addition of a lubricant.

Calculations of the torque required for correct bolt elongation are based on the geometry of the threaded fastener and the friction of the thread and bearing surfaces. The friction factor applied to the torque calculations is known as the K factor. The friction coefficients of the thread and bolt head are used to calculate the K factor. It is therefore through lubrication that friction and K-factor can be controlled to ensure correct bolt tension and elongation for a derived torque value.

During assembly, torque energy is first consumed to overcome friction. The remaining energy is consumed by the elongation of the bolt (which provides the clamping force). In the absence of adequate lubrication, too much torque is used to overcome friction, resulting in insufficient bolt elongation.

K-factor formula

Defined failure mechanisms

 

Unequal coefficients of friction (µ)

  • High µ of contacting surfaces (head, nuts, shank and threads) can lead to increased twisting of the fastener and reduced clamping force.
  • A low µ of the surfaces in contact can lead to excessive elongation of the bolt

 

Adhesive sliding

 

The difference between static friction and kinetic friction when two surfaces are in contact

 

Stress corrosion cracking

 

At high temperatures, sulphur diffuses into the interstices of joints, creating high stress points. The sulphur then combines with the nickel (in alloy steels) to form sulphide crystals. These crystals grow, increasing stress and creating larger cracks.

 

Contact wear

 

Vibration causes the oxide layers to wear, and the particles clog the internal spaces, leading to seizure.

 

Abrasion

 

Sliding detaches the oxide layer from the threaded materials, the roughness is transferred and destroys the surface and the coating.

 

Seizure

 

Oxide-free surfaces become cold-welded under extreme pressure, preventing disassembly.

 

Not all lubricants are created equal

 

Different by design

 

Greases, anti-seize pastes and anti-friction coatings are formulated to meet different challenges and keep equipment running smoothly.

Greases contain high concentrations of base oils to create the lubricating film between surfaces. Anti-seize pastes and anti-friction coatings are formulated differently. The base oil in these materials simply carries the high concentration of solid lubricants directly to the point of lubrication. These solid lubricants do not evaporate, ensuring effective lubrication even under high temperatures and pressures.

For durable assembly and disassembly of threaded connections, the lubricant must remain in place, even in harsh environments. Molykote® anti-seize pastes and anti-friction coatings offer effective long-term solutions. These lubrication solutions form a protective layer between threaded surfaces, facilitating assembly and disassembly while protecting against wear and corrosion.

Greases are designed to purge base oils for lubrication, but in threaded connections the lubricant may not be able to withstand the high load and the base oil may evaporate, reducing the life of the grease.

Molykote anti-seize pastes contain a high concentration of solid lubricants, offering protection against abrasion, fretting corrosion, slippage, seizure and damage. They offer corrosion protection, water washout resistance and a consistent coefficient of friction. These solid lubricants stay in place, even at high temperatures and under heavy loads.

Anti-friction coatings are paint-like products that form a slippery film on the surface, optimising friction control even under extreme conditions. Their effectiveness and service life are highly dependent on the pre-treatment of the component surface, such as degreasing, phosphating, sandblasting and anodising.

 

Typical properties of solid lubricants used in anti-seize paste and anti-friction coating formulations

By combining different types of solid lubricants in paste formulations, we achieve increased protection against fretting corrosion, improved load carrying capacity and wear prevention. The combination of these lubricants offers more than they do individually.

 

Graphite Molybdenum disulphide (MoS2) Polytetrafluoroethylene (PTFE) Copper White solids
High temperature stability High load-bearing capacity Colourless High load-bearing capacity Protects against fretting corrosion
Good lubricant in wet conditions Wide temperature range Low load-bearing capacity High temperature stability Suitable for high temperatures
Low coefficient of friction at high loads Excellent adhesion Low coefficient of friction at low loads Should not be used with stainless steel at temperatures above 1000°C (1832°F) Excellent adhesion
Protects against fretting corrosion Protects against fretting corrosion Good chemical resistance Can promote galvanic corrosion
Friction decreases with increasing load Good reduction in sliding friction
Prevents sticking and sliding
Should not be used in damp environments

 

Anti-seize pastes

 

Molykote® anti-seize pastes are high performance products specially formulated for extreme conditions, creating and maintaining a lubricating layer despite high loads and temperatures. They offer:

 

  • Wear protection
  • Reliable performance over wide temperature ranges
  • Constant coefficient of friction (µ)
  • Resistance to water washout
  • Protection against corrosion
  • Immediate lubrication on application and long-term lubrication

 

Anti-seize pastes can be applied by brushing or dispensed pumping, and some are available in sprays.

 

Anti-friction coatings

 

Molykote® anti-friction coatings are ideal for parts exposed to dusty or inaccessible environments, providing long-term lubrication. Parts can be pre-lubricated in a clean environment to reduce handling during field assembly operations.

Molykote® brand AFCs (Anti-Friction Coatings) are formulated to offer these benefits when cured:

 

  • Dry lubrication
  • Non-flammable coating
  • Film does not attract dirt and dust
  • Extra protection against corrosion
  • Long-term lubrication without evaporation
  • Effective lubrication even after extended service life

 

Application methods include spraying, dipping, centrifuging, brushing and roller coating.

 

Is dry lubrication necessary?

 

If your application is exposed to dust, dirt and debris, Molykote® antifriction coatings are recommended. If not, choose Molykote® anti-seize pastes.

 

Can your part be thoroughly cleaned and dried?

 

If so, choose Molykote® anti-friction coatings. If not, choose Molykote® anti-seize pastes.

 

Select the right lubricant

 

The Molykote anti-seize pastes and anti-friction coatings (AFCs) featured in this brochure are specially formulated for use on threaded connections, ensuring long-term protection, reliability and productivity.

Anti-seize pastes do not require extensive surface preparation, while anti-friction coatings require thoroughly cleaned and dried surfaces. Used together, Molykote® anti-seize pastes and AFCs can offer synergistic performance.

You can use the following tables to select the Molykote lubricant that best meets your needs. For more information and technical specifications please contact us.

Selection table for Molykote anti-seize pastes

 

Using anti-seize pastes is one of the best ways to reduce and control friction in threaded connections, ensuring long-term performance and easy disassembly and reassembly. To determine the appropriate anti-seize paste, consider the load, environment, temperature and speed of your application. Below is a general description of the Molykote anti-seize pastes that DuPont considers most suitable for threaded connections.

 

1 Temperature range of solid lubricants

PRODUCT NAME MAIN FEATURES TEMP. RANGE (in °C) SOLID LUBRICANTS High adhesion capacity Composition metal-free Prevention against fretting corrosion Protection against fretting corrosion Water resistance High load capacity Suitable for low to moderate loads
MOLYKOTE® G-n METAL ASSEMBLY PASTE/SPRAY
  • Suitable for general assembly and lapping
Up to 400¹ White solids, MoS2
MOLYKOTE® G-n PLUS PASTE
  • Copper-free
Up to 400 MoS2, graphite, white solids
MOLYKOTE® G-RAPID PLUS PASTE/SPRAY
  • Provides a consistently low coefficient of friction
Up to 400 MoS2, graphite, white solids
MOLYKOTE® 1000 PASTE/SPRAY
  • Ideal for high load, high vibration applications where constant torque is required
-30 to 650 Copper and graphite, white solids
MOLYKOTE® M-77 PASTE
  • Silicone base oil offers greater stability.
  • Remains pasty at higher temperatures.
  • Compatible with many elastomers and plastics.
Up to 350¹ MoS2
MOLYKOTE® P-37 PASTE
  • High purity
  • Suitable for stainless, austenitic and high nickel-chromium steels
  • Prevents stress corrosion cracking and weld embrittlement.
-30 to 1400¹ Zirconium dioxide
MOLYKOTE® P-40 PASTE
  • Metal-free
  • Suitable for contact with water
-40 to 1200¹ White solids and PTFE
MOLYKOTE® P-74 PASTE
  • Synthetic base oil carrier
  • Remains grease-like for a longer period of time
-40 to 200 Graphite and white solids
MOLYKOTE® P-1900 PASTE / SPRAY
  • Suitable for food processing machines
  • FDA 21 CFR 178.3570
  • NSF H1 approved
-30 to 300 White solids
MOLYKOTE® U-n PASTE
  • Polyalkylene glycol (PAG) base oil
  • Extremely tacky
  • Compatible with natural rubber
Up to 400¹ MoS2 and white solids

Molykote® brand Anti-Friction Coating (AFC) Selection Chart.

 

The use of an AFC is one of the best ways to reduce and control friction in threaded connections, ensure long-term performance and facilitate disassembly and reassembly. When determining the appropriate AFC, remember to consider the service requirements, the desired coating method and the specific benefits of different applications. Below are general descriptions of the Molykote AFCs that DuPont considers most suitable for threaded connections.

 

PRODUCT NAME MAIN CHARACTERISTICS TEMP. RANGE (in °C) SOLID / BINDING LUBRICANTS High load Chemical resistance Fuel and oil resistance Contact corrosion Corrosion resistance
MOLYKOTE® 3402-C ANTIFRICTION COATING
  • Curing at ambient temperature
  • High resistance to pressure and wear
-200 to 310 Solids: MoS₂ Binder: proprietary
MOLYKOTE® D-708 ANTIFRICTION COATING
  • Heat hardening
  • Gloss black finish
-64 to 240 Solids: PTFE Binder: epoxy
 MOLYKOTE® D-7409 ANTIFRICTION COATING
  • Heat curing
  • Suitable for high temperatures
-70 to 300 Solids: MoS₂ Binder: polyamide-imide
MOLYKOTE® 3400A ANTIFRICTION COATING / SPRAY
  • Thermal cure
  • Excellent adhesion
-200 to 260 Solids: MoS₂ Binder: epoxy
MOLYKOTE® D-321R ANTIFRICTION COATING / SPRAY
  • Cures at room temperature
  • Available as an aerosol spray
-200 to 260 Solids: MoS₂, graphite Binder: titanate
MOLYKOTE® 106 ANTIFRICTION COATING
  • Heat curing
  • Easy to apply
-70 to 250 Solids: MoS₂ Binder: epoxy

 

Source: Molykote Technical Documents

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